Dangerous goods are solids, liquids, or gases that can harm people, other living organisms, property, or the environment.
They are often subject to chemical regulations. "HazMat teams" are personnel specially trained to handle dangerous goods.
Dangerous goods are radioactive, flammable, explosive, corrosive, oxidizing, asphyxiating, bio hazardous, toxic, pathogenic, or allergenic.
Also included are physical conditions such as compressed gases and liquids or hot materials, including all goods containing such materials or chemicals, or may have other characteristics that render them hazardous in specific circumstances.
Dangerous goods are often indicated by diamond-shaped signage.
The colours of each diamond in a way has reference to its hazard i.e.:
Flammable = red because fire and heat are generally of red colour,
Explosive = orange, because mixing red (flammable) with yellow (oxidising agent) creates orange.
Non Flammable Non Toxic Gas = green, due to all compressed air vessels being this colour in France after World War II.
France is where the diamond system of HazMat identification originated.
Classification and labeling summary tables
Class 1: Explosives
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Hazardous Materials |
Class 1: Explosives |
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Hazardous Materials |
Class 1.1: Explosives |
Mass Explosion Hazard |
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Hazardous Materials |
Class 1.2: Explosives |
Blast/Projection Hazard |
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Hazardous Materials |
Class 1.3: Explosives |
Minor Blast Hazard |
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Hazardous Materials |
Class 1.4: Explosives |
Major Fire Hazard |
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Hazardous Materials |
Class 1.5: Blasting Agents |
Blasting Agents |
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Hazardous Materials |
Class 1.6: Explosives |
Extremely Insensitive Explosives |
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Class 2: Gases
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Hazardous Materials |
Class 2.1: Flammable Gas |
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Hazardous Materials |
Class 2.2: Nonflammable Gas |
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Hazardous Materials |
Class 2.3: Poisonous Gas |
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Hazardous Materials |
Class 2.2: Oxygen (Alternative Placard) |
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Hazardous Materials |
Class 2.3: Inhalation Hazard (Alternative Placard) |
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Class 3: Flammable Liquids
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Hazardous Materials |
Class 3: Flammable Liquids |
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Hazardous Materials |
Class 3: Combustible (Alternate Placard) |
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Hazardous Materials |
Class 3: Fuel Oil (Alternate Placard) |
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Hazardous Materials |
Class 3: Gasoline (Alternate Placard) |
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Class 4: Flammable Solids
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Hazardous Materials |
Class 4.1: Flammable Solids |
4.1 Flammable Solids: Solid substances that are easily ignited and readily combustible (nitrocellulose, magnesium, safety or strike-anywhere matches). |
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Hazardous Materials |
Class 4.2: Spontaneously Combustible Solids |
4.2 Spontaneously Combustible: Solid substances that ignite spontaneously (aluminium alkyls, white phosphorus). |
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Hazardous Materials |
Class 4.3: Dangerous when Wet |
4.3 Dangerous when Wet: Solid substances that emit a flammable gas when wet or react violently with water (sodium, calcium, potassium, calcium carbide). |
Class 5: Oxidizing Agents and Organic Peroxides
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Hazardous Materials |
Class 5.1: Oxidizing Agent |
5.1 Oxidizing agents other than organic peroxides (calcium hypochlorite, ammonium nitrate, hydrogen peroxide,potassium permanganate).
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Hazardous Materials |
Class 5.2: Organic Peroxide Oxidizing Agent |
5.2 Organic peroxides, either in liquid or solid form (benzoyl peroxides, cumene hydroperoxide).
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Class 6: Toxic and Infectious Substances
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Hazardous Materials |
Class 6.1: Poison |
- 6.1a Toxic substances which are liable to cause death or serious injury to human health if inhaled, swallowed or by skin absorption (potassium cyanide, mercuric chloride).
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Hazardous Materials |
Class 6.2: Biohazard |
- 6.2 Biohazardous substances; the World Health Organization (WHO) divides this class into two categories: Category A: Infectious; and Category B: Samples (virus cultures, pathology specimens, used intravenous needles).
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Class 7: Radioactive Substances
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Hazardous Materials |
Class 7: Radioactive |
Radioactive substances comprise substances or a combination of substances which emit ionizing radiation (uranium, plutonium).
Class 8: Corrosive Substances
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Hazardous Materials |
Class 8: Corrosive |
Corrosive substances are substances that can dissolve organic tissue or severely corrode certain metals:
8.1 Acids: sulfuric acid, hydrochloric acid
8.2 Alkalis: potassium hydroxide, sodium hydroxide
Other hazardous materials labels (CHIP)
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Hazardous Materials |
Hazard Symbol: C/Corrosive |
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Hazardous Materials |
Hazard Symbol: E/Explosive |
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Hazardous Materials |
Hazard Symbol: F/Flammable |
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Hazardous Materials |
Hazard Symbol: N/Environmental Hazard |
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Hazardous Materials |
Hazard Symbol: O/Oxidizing |
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Hazardous Materials |
Hazard Symbol: T/Toxic |
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Hazardous Materials |
Hazard Symbol: Xn/Harmful; Xi/Irritant |
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